세션명 | 고분자구조 및 물성(III) |
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발표장 | 포스터장 |
논문코드 | 3PS-94 |
발표일 | 2019-10-11 |
발표시간 | 16:00-17:30 (게시시간: 13:50-17:30) |
논문제목 | High-density HEX Cylindrical Microdomains Using Blends of Block Copolymers |
발표자 | 강석원 |
발표자 소속 | POSTECH |
저자 | 강석원, 김진곤† |
소속 | POSTECH |
논문초록 | This study presents a binary blend of block copolymers that fabricates inverted cylindrical microdomains. This blend system consists of polystyrene-block-poly(2-vinylpyridine) (PS-b-P2VP) and polystyrene-block-poly(hydroxylstyrene) (PS-b-PHS). Hydrogen bond interactions occur between P2VP and PHS and affect the interface curvature and the phase behavior of binary blends. The blends formed hexagonally-packed cylindrical microdomains and the volume fraction of the cylinder parts was > 0.6. The morphology of blends was unexpected in comparison with usual block copolymer systems and achieved high-density HEX cylindrical patterns. |