THE POLYMER SOCIETY OF KOREA

연구논문 초록집

초록 검색

세션명 고분자구조 및 물성(III)
발표장 포스터장
논문코드 3PS-94
발표일 2019-10-11
발표시간 16:00-17:30 (게시시간: 13:50-17:30)
논문제목 High-density HEX Cylindrical Microdomains Using Blends of Block Copolymers
발표자 강석원
발표자 소속 POSTECH
저자 강석원, 김진곤
소속 POSTECH
논문초록 This study presents a binary blend of block copolymers that fabricates inverted cylindrical microdomains. This blend system consists of polystyrene-block-poly(2-vinylpyridine) (PS-b-P2VP) and polystyrene-block-poly(hydroxylstyrene) (PS-b-PHS). Hydrogen bond interactions occur between P2VP and PHS and affect the interface curvature and the phase behavior of binary blends. The blends formed hexagonally-packed cylindrical microdomains and the volume fraction of the cylinder parts was > 0.6. The morphology of blends was unexpected in comparison with usual block copolymer systems and achieved high-density HEX cylindrical patterns.